Prochloraz copper complex |
Last updated: 03/03/2024 |
(Also known as: prochloraz-Cu) |
SUMMARY |
Data alerts |
The following alerts are based on the data in the tables below. An absence of an alert does not imply the substance has no implications for human health, biodiversity or the environment but just that we do not have the data to form a judgement.
Environmental fate | Ecotoxicity | Human health |
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A prochloraz-metal complex active against a wide range of fungal diseases affecting cereals, field crops, fruit and many other crops | |
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Anthracnose; Dothiorella complex; Stem-end rot; Eyespot | |
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Fruit; Field crops; Mushrooms; Turf; Avocados; Mangoes; Cereals including wheat, barley, winter rye, winter oilseed rape | |
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Wheat/Eyespot=Moderate; Wheat/Mildew=Low; Wheat/Septoria=Low; Wheat/Rust=Low; Barley/Net blotch=Low | |
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Current | |
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1977, prochloraz first reported |
UK regulatory status |
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Approved - as prochloraz | ||
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31/12/2026 | ||
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Check label - may vary with formulation |
EC Regulation 1107/2009 (repealing 91/414) |
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Not approved | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||
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Belgium/Denmark | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||
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Expired | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||
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Not applicable | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||
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Yes (as prochloraz) | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||
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Additional information |
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Chemical structure |
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None | |
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C₆₀H₆₄Cl₁₄CuN₂O₈ | |
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No |
General status |
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Fungicide | |
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Amide fungicide; Conazole fungicide; Organometal complex; Organocopper fungicide | |
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Synthetic | |
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Broad-spectrum with protectant and eradicant properties. Disrupts membrane function. | |
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156065-03-1 | |
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No data found | |
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407 | |
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- | |
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381392645 | |
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No data found | |
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1641.11 | |
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- | |
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Copper(2+),tetrakis[N-propyl-N-[2-(2,4,6-trichlorophenoxy)ethyl]-1H-imidazole-1-carboxamide-.kappa.O1]-,dichloride | |
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- | |
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UK non-statutory standard for the protection of aquatic life: freshwater and saltwater annual average: 4 ug prochloraz/L; max acceptable conc: 40 ug prochloraz/L | |
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Not applicable | |
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Not applicable | |
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Not applicable | |
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3 | |
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Formulations |
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Often used as a seed treatment. |
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499.8 | Q3 Q = Miscellaneous data from online sources 3 = Unverified data of known source |
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256.1 | Q3 Q = Miscellaneous data from online sources 3 = Unverified data of known source |
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1.62 X 1003 | Calculated | - | |||||||
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3.21 | Q3 Q = Miscellaneous data from online sources 3 = Unverified data of known source |
High | ||||||||
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Degradation |
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Not readily biodegradable | ||||||||||
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The copper complex will rapidily dissociate - see prochloraz data | ||||||||||
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As this parameter is not normally measured directly, a surrogate measure is used: ‘Photochemical oxidative DT₅₀’. Where data is available, this can be found in the Fate Indices section below. | ||||||||||
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Soil adsorption and mobility |
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- | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) 5 = Verified data used for regulatory purposes |
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The copper complex will rapidily dissociate - see prochloraz data | ||||||||||
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- | A4 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) 4 = Verified data |
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The copper complex will rapidily dissociate - see prochloraz data | ||||||||||
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Fate indices |
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Cannot be calculated | - | - | |||||||||||||||||||||||||
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Known soil metabolites |
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Major fraction | - | - |
Known groundwater metabolites |
None
Other known metabolites |
None
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Terrestrial ecotoxicology |
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> 2000 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) Rat5 = Verified data used for regulatory purposes |
Low | ||||||||
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662 | A4 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) Colinus virginianus as prochloraz4 = Verified data |
Moderate | ||||||||
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33.1 | A4 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) Colinus virginianus as prochloraz NOEC4 = Verified data |
Moderate | ||||||||
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> 1000 | A4 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) Eisenia foetida a prochloraz4 = Verified data |
Low | ||||||||
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141.3 | A4 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) Apis mellifera as prochloraz4 = Verified data |
Low | |||||||
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> 101 | A4 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) Apis mellifera as prochloraz4 = Verified data |
Low | ||||||||
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> 900 | A4 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) Coccinella septempunctata as prochloraz4 = Verified data |
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85.1 | A4 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) Aphidius rhopalosiphi as prochloraz4 = Verified data |
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44.3 | A4 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) Typhlodromus pyri as prochloraz4 = Verified data |
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0 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) Poecilus cupreus5 = Verified data used for regulatory purposes |
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Aquatic ecotoxicology |
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1.5 | A4 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) Oncorhynchus mykiss as prochloraz4 = Verified data |
Moderate | ||||||||
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0.049 | A4 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) Pimephales promelas as prochloraz4 = Verified data |
Moderate | ||||||||
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4.3 | A4 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) Daphnia magna as prochlorax4 = Verified data |
Moderate | ||||||||
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0.022 | A4 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) Daphnia magna as prochloraz4 = Verified data |
Moderate | ||||||||
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0.0055 | A4 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) Scenedesmus subspicatus as prochloraz4 = Verified data |
High | ||||||||
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General |
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High (class III) | - | - | ||||||||
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> 2000 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) Rat5 = Verified data used for regulatory purposes |
Low | ||||||||
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5000 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) Rat5 = Verified data used for regulatory purposes |
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0.01 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) Dog SF=100 as prochloraz5 = Verified data used for regulatory purposes |
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0.025 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) Rat SF=100 as prochloraz5 = Verified data used for regulatory purposes |
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0.02 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) Dog SF=100 as prochloraz5 = Verified data used for regulatory purposes |
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1.2-3.2 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) concentration dependent5 = Verified data used for regulatory purposes |
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No unacceptable risks to bystanders identified | |||||||||
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No unacceptable risks to operators or other workers identified | ||||||||||
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0.1 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) EU Dir 89/778/EC limit; Calc MAC=30 µg prochloraz/L5 = Verified data used for regulatory purposes |
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Health issues |
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Possible liver toxicant US EPA - possible human carcinogen Endocrine issues - Activation of Pregnane X cellular receptor |
Handling issues |
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IMDG Transport Hazard Class 9 Not expected to auto-ignite; Not highly flammable May be explosive depending on product formulation |
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Health: H302 Environment: H400, H410 |
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II (Moderately hazardous) | |||
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UN3077 | |||
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Contain/absorb spillage in suitable inert, absorbent material. Transfer to heavy duty plastic drums. Dispose in approved manner Packaging Group III (minor danger) |
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prochloraz copper complex | ||
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prochloraze-manganèse | ||
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Record last updated: | 03/03/2024 |
Contact: | aeru@herts.ac.uk |
Please cite as: | Lewis, K.A., Tzilivakis, J., Warner, D. and Green, A. (2016) An international database for pesticide risk assessments and management. Human and Ecological Risk Assessment: An International Journal, 22(4), 1050-1064. DOI: 10.1080/10807039.2015.1133242 |