Chlorphoxim (Ref: OMS 1197) |
Last updated: 24/07/2024 |
(Also known as: chlorphoxime; Bayer 78182; BAY 78182; BAY SRA 7747) |
SUMMARY |
Chlorphoxim is an organophosphate insecticide. Little information is available regading its environmental fate It is highly toxic to birds but has a low fish toxicity. Mammalian toxicity is also considered to be low but chlorphoxim is a cholinesterase inhibitor and a neurotoxin. |
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Chlorphoxim is an obsolete public health insecticide | |
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Considered obsolete but may be available in some countries | |
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1972, first reported | |
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Approval status |
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Chemical structure |
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Isomeric, Substance has one E/Z centre | |
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C₁₂H₁₄ClN₂O₃PS | |
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CCOP(=S)(OCC)ON=C(C#N)C1=CC=CC=C1Cl | |
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CCOP(=S)(OCC)O/N=C(/C#N)\C1=CC=CC=C1Cl | |
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GQKRUMZWUHSLJF-UHFFFAOYSA-N | |
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InChI=1S/C12H14ClN2O3PS/c1-3-16-19(20,17-4-2)18-15-12(9-14)10-7-5-6-8-11(10)13/h5-8H,3-4H2,1-2H3 | |
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Yes |
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Common Name | Relationship | Link |
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chlorphoxim | - |
General status |
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Organophosphate insecticide; Organothiophosphate insecticide | |
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Synthetic | |
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Acetylcholinesterase (AchE) inhibito - after conversion to the oxygen analogue | |
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14816-20-7 | |
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238-888-9 | |
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341 | |
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Not listed | |
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5360461 | |
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No data found | |
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332.74 | |
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O,O-diethyl ({[(?)-(2-chlorophenyl)cyanomethylidene]amino}oxy)phosphonothioate | |
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O,O-diethyl 2-chloro-α-cyanobenzylideneaminooxyphosphonothioate | |
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7-(2-chlorophenyl)-4-ethoxy-3,5-dioxa-6-aza-4-phosphaoct-6-ene-8-nitrile 4-sulfide | |
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PAN Bad Actor Chemical | |
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White crystalline solid |
Formulations |
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1.7 | V3 V = ChemID Online Databases; Chemspider; PubChem. (ChemID ) at 25 °C3 = Unverified data of known source |
Low | ||||||||
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66.5 | F3 F = U.S. EPA ECOTOX database / U.S. EPA pesticide fate database / Miscellaneous WHO documents / FAO data, IPCS INCHEM data (US EPA Databases Related to Pesticide Risk Assessment ) 3 = Unverified data of known source |
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1.07 X 1005 | Calculated | - | |||||||
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5.03 | V3 V = ChemID Online Databases; Chemspider; PubChem. (ChemID ) 3 = Unverified data of known source |
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Degradation |
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As this parameter is not normally measured directly, a surrogate measure is used: ‘Photochemical oxidative DT₅₀’. Where data is available, this can be found in the Fate Indices section below. | ||||||||||
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Soil adsorption and mobility |
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Fate indices |
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Known metabolites |
None
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Terrestrial ecotoxicology |
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> 2500 | F3 F = U.S. EPA ECOTOX database / U.S. EPA pesticide fate database / Miscellaneous WHO documents / FAO data, IPCS INCHEM data (US EPA Databases Related to Pesticide Risk Assessment ) Rat3 = Unverified data of known source |
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50 | F3 F = U.S. EPA ECOTOX database / U.S. EPA pesticide fate database / Miscellaneous WHO documents / FAO data, IPCS INCHEM data (US EPA Databases Related to Pesticide Risk Assessment ) Colinus virginianus3 = Unverified data of known source |
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Aquatic ecotoxicology |
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120 | F3 F = U.S. EPA ECOTOX database / U.S. EPA pesticide fate database / Miscellaneous WHO documents / FAO data, IPCS INCHEM data (US EPA Databases Related to Pesticide Risk Assessment ) Cyprinus carpio3 = Unverified data of known source |
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General |
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High (class III) | - | - | ||||||||
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> 2500 | F3 F = U.S. EPA ECOTOX database / U.S. EPA pesticide fate database / Miscellaneous WHO documents / FAO data, IPCS INCHEM data (US EPA Databases Related to Pesticide Risk Assessment ) Rat3 = Unverified data of known source |
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500 | V3 V = ChemID Online Databases; Chemspider; PubChem. (ChemID ) Rat3 = Unverified data of known source |
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0.3 | F3 F = U.S. EPA ECOTOX database / U.S. EPA pesticide fate database / Miscellaneous WHO documents / FAO data, IPCS INCHEM data (US EPA Databases Related to Pesticide Risk Assessment ) Rat 4 hr3 = Unverified data of known source |
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List I | - | - | ||||||||
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Absorbed from gastrointestinal tract and skin | |||||||||
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Health issues |
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No further information available |
Handling issues |
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IMDG Transport Hazard Class 6.1 | |||
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Health: H311 | |||
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U (Unlikely to present an acute hazard) | |||
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UN2783 | |||
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chlorphoxim | ||
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chlorphoxime | ||
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Chlorphoxim | ||
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Clorfoxim | ||
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Record last updated: | 24/07/2024 |
Contact: | aeru@herts.ac.uk |
Please cite as: | Lewis, K.A., Tzilivakis, J., Warner, D. and Green, A. (2016) An international database for pesticide risk assessments and management. Human and Ecological Risk Assessment: An International Journal, 22(4), 1050-1064. DOI: 10.1080/10807039.2015.1133242 |